- Chris Evans
- Steve Rogers/Captain America
- Scarlett Johansson
- Natasha Romanoff/Black Widow
- Samuel L. Jackson
- Nick Fury
- Sebastian Stan
- Bucky Barnes/Winter Soldier
- Robert Redford
- Agent Alexander Pierce
- Anthony Mackie
- Sam Wilson/Falcon
- Cobie Smulders
- Maria Hill
- Frank Grillo
- Brock Rumlow/Crossbones
- Emily VanCamp
- Sharon Carter/Agent 13
- Hayley Atwell
- Peggy Carter
- Toby Jones
- Arnim Zola
- Stan Lee
- Museum Staff, Executive Producer
- Callan Mulvey
- Jack Rollins
- Jenny Agutter
- World Security Council Member
- Bernard White
- Councilman Nagendra Singh
- Anthony Russo
- Director
- Joe Russo
- Director
- Christopher Markus
- Screenwriter
- Stephen McFeely
- Screenwriter
- Kevin Feige
- Producer
- Alan Fine
- Executive Producer
- Louis D'Esposito
- Executive Producer
- Victoria Alonso
- Executive Producer
- Michael Grillo
- Executive Producer
- Stan Lee
- Museum Staff, Executive Producer
- Trent Opaloch
- Cinematographer
- Peter Wenham
- Production Design
- Jeffrey Ford
- Film Editing
- Mary Jo Markey
- Film Editing
- Henry Jackman
- Original Music
- Leslie Pope
- Set Decoration
- Mic Rodgers
- Stunts
- Beat Frutiger
- Art Director
- Kevin Ishioka
- Art Director
- Judianna Makovsky
- Costume Design
- Sarah Halley Finn
- Casting
